વરિષ્ઠ વૈજ્ વૈજ્ઞાનિક
- ankush@csmcri.res.in
- 2567760 (Extn. 7170) | Ext: 7170
Research Activities
Heterogeneous Catalysis , Synthesis and characterization of Nano, Multifunctional Catalysts (Carbon, Silica, Ceria and Zirconia), Catalysis: Oxidation, Dehydrogenation, Hydrogenation, Carbonylation, Amination, Nitration, Nitro-aldol reactions etc. Gas phase and High Pressure reactions Bio-Materials synthesis
-|| Research Highlights ||-
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54
Advani, J. H.; Singh, A. S.; Khan, H. N.; Bajaj, H. C.; Biradar, A. V. * Black yet green: Sulfonic acid functionalized carbon as an efficient catalyst for highly selective isomerization of α-pinene oxide to trans-carveol” Appl. Catal B. Env. 2019, 118456 IF-14.229
53
J. H. Advani, N. H. Khan, H. C. Bajaj, A. V. Biradar* “Stabilization of palladium nanoparticles on chitosan derived N-doped carbon for hydrogenation of various functional groups” Appl. Surf. Sci. 2019, 487, 1307–1315. IF-5.155
52
R. Krishnan, B. D. Bankar, S. Jindani, A. V. Biradar* Surfactant-Assisted Selective Oxidation of Aromatic Amines to Nitro Compounds by in Situ-Formed Performic Acid ACS Omega 2019, 4, 9453−9457. IF-2.58
51
Doke, D. S.; Advani, J. H.; Naikwadi, D. R.; Gawande, M. B.; Walke, P.; Umbarkar, S. B.; Biradar, A.V.* “Utilization of Waste Biomass for the Synthesis of Functionalizable Support for Covalent Anchoring of Active Organo Catalyst” ACS Sustainable Chem. Eng. 2019, 7, 3018−3026. IF-6.97
50
P. Patel, S. Nandi, T. Menapara, A. V. Biradar, R. K. Nagarale, N. H. Khana, R. I. Kureshy “Glycoluril: A heterogeneous organocatalyst for oxidation of alcohols and benzylic sp3 carbons Appl.Catal. A, Gen. 2018, 565, 127–134. IF-4.63
49
S. Nandi, P. Patel, N. H. Khan, A. V. Biradar, R. I. Kureshy “Nitrogen-rich graphitic-carbon stabilized cobalt nanoparticles for chemoselective hydrogenation of nitroarenes at milder conditions” Inorg. Chem. Front., 2018,5, 806-813 IF- 5.934
48
S. Nandi, P. Patel, A. Jakhar, N. H. Khan, A. V. Biradar, R. I. Kureshy, H. C. Bajaj “Cucurbit[6]uril-Stabilized Palladium Nanoparticles as a Highly Active Catalyst for Chemoselective Hydrogenation of Various Reducible Groups in Aqueous Media” ChemistrySelect 2017, 2, 9911– 9919. IF- 1.716
47.
Doke, D. S.; Umbarkar, S. B.; Gawande, M. B.; Zboril, R.; Biradar, A. V.* “Environmentally Benign Bioderived Carbon Microspheres-Supported Molybdena Nanoparticles as Catalyst for the Epoxidation Reaction” ACS Sustainable Chem. Eng. 2017 5, 904-910 IF- 6.97
46
Khandelwal, N.; Barbole, R. S.; Banerjee, S. S. ; Chate, G. P.;Biradar, A. V. Khandare, J. J. Giri, A. P. Budding trends in integrated pest management using advanced micro- and nano-materials: Challenges and perspectives J. Environ. Manage. 2016, 184, 157-169 IF- 4.175
45.
Gawande, M. B.; Goswami, A.; Asefa, T.; Guo, H.; Biradar, A. V.; Peng, D-L.; Zboril, R.; Varma, R. S. “Core–shell nanoparticles - applications in catalysis and electrocatalysis” Chem. Soc. Rev. 2015, 44, 7540-7590. IF- 40.443
44.
Biradar, A. A.; Biradar, A. V.; Sun, T.; Chan, Y.; Huang,X.; Asefa, T.* Bicinchoninic Acid-Based Colorimetric Chemosensor for Detection of Low Concentrations of Cyanide Sensors & Actuators: B. Chemical 2016, 222, 112–119. IF-6.393
43.
Banerjee, S. S.; Todkar, K. J.; Khutale, G. V.; Chate, G. P.; Biradar, A. V.; Gawande, M. B.; Zboril, R.; Khandare, J. J.* “Calcium Phosphate Nanocapsule Crowned Multiwalled Carbon Nanotubes For pH Triggered Intracellular Anticancer Drug Release” J. Mater. Chem. B, 2015, 3, 3931-3939. IF- 4.776
42.
Biradar, A.V.* Patil, V. S.; Chandra, P.; Doke, D. S.; Asefa,T.* “Trifunctional Mesoporous SBA-15 as a Highly Active Catalyst for One-Pot Tandem Reaction” Chem. Commun., 2015 51, 8496-8499. IF-6.164
41.
Khandelwal, N.; Doke, D. S.; Jawale, P. S.; Khandare, J. J.; Biradar A. V.*; Giri, A. P.* “Bio-physical evaluation and in vivo delivery of proteinase inhibitor functionalized Silica nanospheres” Colloids and Surfaces B: Biointerfaces 2015, 13, 84-92. IF- 3.973
40.
Chandra, P.; Doke, D. S.; Umbarkar, S. B.; Vanka, K.; Biradar, A. V.* “Silica Microspheres with High Density Hydroxyl Groups as an Efficient Epoxidation Catalysts” RSC Adv., 2015, 5, 21125–21131. IF- 3.049
39.
Chandra, P.; Shinde, S. S.; Biradar, A. V.* “Tailor made Ionic Liquids: Catalyst and Media for Organic Transformations” Current Organic Chemistry. 2015, 19, 728-742. IF- 2.157
38.
- Fang, W.; Paul, S.; Capron, M.; Biradar, A. V.; Umbarkar, S. B.; Dongare, M. K.; Dumeignil, F. Jalowiecki-Duhamel, L.. “Highly loaded well dispersed stable Ni species in NiXMg2AlOY nanocomposites: Application to hydrogen production from bioethanol” Appl. Catal. B: Env. 2015,166-167, 485-496. IF- 14.229
37.
Chandra, P.; Doke, D. S.; Umbarkar, S. B.; Biradar, A. V .* One Pot Synthesis of Ultrasmall MoO3 Nanoparticles Supported on SiO2, TiO2, and ZrO2 Nanospheres: An Efficient Epoxidation Catalyst” J. Mater. Chem. A, 2014, 2, 19060-19066. IF- 10.733
36.
Acham, V. R.; Biradar, A. V.; Donagare, M. K.; Umbarkar, S. B.; Kemnitz, E. “Palladium Nanoparticles Supported on Magnesium Hydroxide Fluorides: A Novel Recyclable Catalyst for Selective Olefin Hydrogenation” ChemCatChem 2014, 6, 3182–3191. IF- 4.495
35.
Linguito, S. L.; Padmanabhan, M.; Zhang, X.; Biradar, A.V.; Xu, T.; Emge,T. M.; Asefa,T.; Li, J.* “New polyoxomolybdate compounds Synthesized in situ using liquid 1-butyl-3-methyl-imidazolium tetrafluoroborate as green solvent” New J. Chem., 2013, 37, 2894. IF- 3.069
34.
Kotbagi, T. V.; Biradar, A. V.; Umbarkar, S. B. Dongare, M. K.; “Isolation, Characterization and Identification of Catalytically Active Species in MoO3/SiO2 Catalyst During Solid acid Catalyzed Reactions” ChemCatChem 2013, 5, 1531-1537. IF-4.495
33.
Aburawi, E. H.; Qureshi, M. A.; Oz, D.; Jayaprakash, P. ; Tariq, S.; Hameed, R. S.; Das, S.; Goswami, A.; Biradar, A. V.; Asefa, T.; Souid, A. K.; Adeghate, E.; Howarth, E. “Biocompatibility of Calcined Mesoporous Silica Particles with Ventricular Myocyte Structure and Function” Chem. Res. Tox. 2013, 1, 26-36. IF- 3.278
32.
Chandagude, M. G.; Biradar, A. V.; Kotbagi, T. V.; Puranik, V. G; Dongare, M. K.; Umbarkar, S. B. “Selective Oxidation of Nonrefractory and Refractory Sulfides by Cyclopentadienyl Molybdenum Acetylide Complexes as Efficient Catalysts” Catal. Lett. 2012, 11, 1352-1360. IF- 2.799
31.
Biradar, A. V.; Asefa, T. “Nanosized Gold Catalyzed Oxidation of Alkyl-Substituted Benzenes” Appl. Catal. A: Gen. 2012, 435-436, 19-26. IF- 4.63
30.
Woronowicz, K.; Ahmed, S.; Biradar, A. A.; Biradar, A. V.; Birnie, III D. P.; Asefa, T.; Niederman, R. A. “Near-IR absorbing solar cell sensitized with bacterial photosynthetic membranes” Photochem. Photobio., 2012, 88, 1467–1472. IF- 2.214
29. Zhang,# J.; Biradar#, A. V.; Emge, T. J.; Asefa, T.; Li, J. “A New 2-D Metal-Organic Framework as a Promising Heterogeneous Catalyst for Olefin Epoxidation Reactions” Chem. Commun., 2012, 48, 6541-6543. # equal contribution. IF-6.164 28.
Al Sa
mri M. T.#; Biradar#, A. V.; Balhaj, G.; Shehab, S.; Al-Salam, S.; Tariq, S.; Pramathan, T.; Benedict, S.; Asefa, T. Souid A-K, “Study on In Vitro Biocompatibility of Calcined Mesoporous Silica Particles with Fetal Blood Cells” Int. J. Nanomedicine, 2012, 7, 3111-3121.# equal contribution IF- 4.47127.
Wang, Y.; Biradar, A. V.; Asefa, T. “Assembling Nanostructures for Effective Catalysis: Supported Pd Nanoparticle Multicores Coated by Hollow and Nanoporous ZrO2 Shell” ChemSusChem, 2012, 1, 132-139. IF- 7.804
26.
Biradar, A. V.; Biradar A. A.; Asefa, T. “Silica-Dendrimer Core-Shell Microspheres with Encapsulated Ultrasmall Palladium Nanoparticles: Efficient and Easily Recyclable Heterogeneous Nanocatalysts” Langmuir, 2011, 27, 14408 –14418. IF- 3.683
25.
Silva, R.; Biradar, A. V.; Fabris, L. Asefa, T. “Au/SBA-15 Based Robust and Convenient-to-Use Nanopowder Material for Surface Enhanced Raman Scattering (SERS) with High SERS Enhancement Factor” J. Phy. Chem. C, 2011, 115, 22810 -22817. IF- 4.309
24.
Al-Salam, S.; Al Samri, M. T.; Al Shamsi, M.; Tariq, S.; Benedict, S.; Sudhadevi, M.; Biradar, A.V.; Asefa, T.; Souid, A.-K. “In Vitro Study of Calcined Mesoporous Silica Nanoparticles in Mouse Lung” Toxicol. Sci., 2011, 122, 86 - 99. IF- 4.081
23.
Sharma, K. K.; Biradar, A. V.; Das, S.; Asefa, T. “Bifunctional Organic-Inorganic Mesoporous Catalyst for Tandem Reactions” Eur. J. Inorg. Chem. 2011, 21, 3174 -3182. IF- 2.578 Selected as hot catalysis article by Wiley publications.
22.
Duncan, C. T.; Biradar, A. V.; Asefa, T. “Aminotroponiminate/Aminotroponate-Zinc Complexes Functionalized Mesoporous Silica Catalysts for Intramolecular Hydroamination of Non-Activated Alkenes with Varied Steric and Electronic Properties” ACS Catal. 2011, 1, 736 - 750. IF- 12.221
21.
Biradar, A. V.; Sharma, K. K.; Asefa, T. “Continuous and Selective Henry Reaction Catalyzed by Amine-Supported Nanoporous Catalyst on Fixed-Bed Reactor” Appl. Catal. A: Gen. 2010, 389, 19 - 26. IF-4.63
20.
Duncan, C. T.; Biradar, A. V.; Mishler II, R. E.; Asefa, T. “Trimming Nanostructured Walls while Fluorinating their Surfaces: A Route to Making and Widening Pores of Nanoporous Materials and Efficient Nanocatalysts” Chem. Mater. 2010. 22, 4950 - 4963. IF- 10.159
19.
Shamsi, A. M.; A. Samri, M. T.; Al-Salam, S.; Conca, W.; Shaban, S.; Benedict, S.; Tariq, S.; Biradar, A.V; Penefsky, H. S.; Asefa, T.; Souid, A.-K. “Biocompatibility of Calcined Mesoporous Silica Particles with Cellular Bioenergetics in Murine Tissues” Chem. Res. Tox. 2010, 23, 1796 - 1805. IF- 3.274
18.
Wang, Y.; Biradar, A. V.; Duncan, C. T.; Asefa, T. “Silica nanosphere-supported shaped Pd nanoparticles encapsulated with nanoporous silica shell: Efficient and recyclable nanocatalysts” J. Mater. Chem. 2010, 20, 7834 – 7841.
17.
Wang, Y.; Biradar, A. V.; Wang, G.; Sharma K. K.; Asefa, T. “Controlled Synthesis of Cuboctahedral Copper Nanoparticles in Aqueous Phase and their Catalytic Properties” Chem. Eur. J. 2010, 16, 10735 - 10743. IF-5.16
16.
Biradar, A. A.; Biradar A. V.; Asefa, T. “Entrapping Flavin-Containing Monooxygenase on Corrugated Silica Nanospheres and their Recyclable Biocatalytic Activities” ChemCatChem 2010, 8, 1004 - 1010. IF-4.495
15.
Sharma, K. K.; Biradar, A. V.; Asefa T. “Substituent and Catalyst-Dependent Selectivity to Aldol or Nitrostyrene Product in Heterogeneous Base Nanocatalysis” ChemCatChem, 2010, 2, 61 - 66. IF- 4.495
14.
Umbarkar, S. B.; Kotbagi, T. V.; Biradar, A. V.; Pasricha, R.; Chanale, J.; Dongare, M. K. Mamede, A-S.; Lancelot, C.; Payen, E. “Acetalization of glycerol using mesoporous MoO3/SiO2 solid acid catalyst” J. Mol. Catal.: A Chem. 2009, 310, 150 - 158. Top 25 hottest article October to December 2009 Top 25 hottest article of Academic Year October 2009 – September 2010
13.
Mishler, II, R. E.; Biradar, A. V.; Duncan, C. T.; Schiff, E. A.; Asefa, T.* “Solvent-washable polymer templated synthesis of mesoporous materials and solid-acid nanocatalysts in one-pot” Chem. Commun. 2009, 6201 - 6203. IF- 6.164
12.
Xie, Y.; Sharma, K. K.; Anan, A.; Wang, G.; Biradar, A. V.; Asefa, T.* “Efficient solid-base catalysts for aldol reaction by optimizing the density and type of organoamine groups on nanoporous silica” J. Catal. 2009, 265, 131 - 140. IF- 7.723 Top 25 hottest article July to September 2009
11.
Biradar, A. V.; Dongare, M. K.; Umbarkar, S. B. “Selective oxidation of aromatic primary alcohols to aldehydes using molybdenum acetylideoxo-peroxo complex as catalyst” Tetrahedron Lett. 2009, 50, 2885 - 2888. IF-2.379
10.
Pasricha, R.; Bala, T.; Biradar, A, V.; Umbarkar, S. B.; Sastrym, M. “Synthesis of Catalytically Active Porous Platinum Nanoparticles by Transmetallation Reaction and Proposition of the Mechanism” Small, 2009, 5, 1467 - 1473. IF-10.856
9.
Biradar, A. V.; Kotbagi, T. V.; Dongare, M. K.; Umbarkar, S. B.“Selective N-oxidation of aromatic amines to nitroso derivatives using a molybdenum acetylideoxo-peroxo complex as catalyst” Tetrahedron Lett., 2008, 49, 3616 - 3619. IF-2.379 (Highlighted in Catalysts & Catalyzed Reactions RSC Publications July 2008 )
8.
Biradar, A. V.; Sathe, B. R.; Umbarkar, S. B.; Dongare, M. K. “Selective cis-Dihydroxylation of Olefins using Recyclable Homogeneous Molybdenum Acetylide Catalyst” J. Mol. Catal.: A Chem. 2008, 285, 111 - 119.
7.
Armbruster, U.; Umbarkar, S. B.; Biradar, A. V.; Dongare, M. K.; Datta, A.; Darmora, S. Martin, A.; Influence of operating method on reforming of glycerol in aqueous phase, U. DGMK Tagungsbericht, 2008, 3, 169-176.
6.
Kamble, V. T.; Ekhe, V. R.; Joshi, N. S.; Biradar, A. V. “Magnesium Perchlorate: An Efficient Catalyst for One-Pot Synthesis of Pyrano- and Furanoquinolines” Synlett, 2007, 9, 1379 - 1382. IF- 2.369
5.
Kamble, V. T.; Jamode, V. S.; Joshi, N. S.; Biradar A. V.; Deshmukh, R. Y. “An efficient method for the synthesis of acylals from aldehydes using silica-supported perchloric acid (HClO4–SiO2)” Tetrahedron Lett., 2006, 47, 5573 - 5576. IF- 2.379
4.
Umbarkar, S. B.; Biradar,A. V.; Mathew, S. M.; Shelke, S. B.; Malshe, K. M.; Patil, P. T.; Dagde, S. P.; Niphadkar S. P.; Dongare,M. K. “Vapor phase nitration of benzene using mesoporous MoO3/SiO2 solid acid catalyst” Green Chem., 2006, 8, 488 - 493. IF-9.405
3.
Mathew, S. M.; Biradar, A. V.; Umbarkar, S. B.; Dongare, M. K. “Regioselective nitration of cumene to 4-nitro cumene using nitric acid over solid acid catalyst” Catal. Commun. 2006, 7, 394 - 398. IF-3.674
2.
Biradar, A. V.; Umbarkar, S. B.; Dongare, M. K. “Transesterification of diethyl oxalate with phenol using MoO3/SiO2 catalyst” Appl. Catal. A: Gen., 2005, 285, 190 - 195. IF- 4.63
1.
Bandgar, B. P.; Kamble, V. T.; Biradar, A. V. “Practical and General Method for Direct Synthesis of Alkyl Fluorides from Alcohols under Mild Conditions” Monat. Fur Chemie, 2005, 136, 1579 - 1582. IF- 1.501
- A. V. Biradar, N. H. Khan, H. C. Bajaj, D. Naikawadi, R. Krishnan “Process for the preparation of flavouring ketones” 21-06-2019 (application number 201911024665).
- N. H. Khan, R. I. Kureshy, A. V. Biradar, P. Patel, B. D. Bankar H. C. Bajaj Iridium catalyst, method of preparation and its use for the preparation of formate/ formic acid” Application no. =201811030629
- Umbarkar, S. B.; Dongare, M. K.; Biradar, A. V.; More, P. M. “Development of non noble metal based diesel oxidation catalyst” INV-2013-144
- Biradar, A. V.; Umbarkar, S. B.; “Synthesis of Functionalized carbon microspheres and their catalyst activity in C-C and C-N bond formation reactions” Pub. No. WO2014207765 (A2) ― WO2014207765-A2; WO2014207765-A32014-12-31 IND patent no 302867 Granded, IND patent no 298372 Granded.
- Umbarkar, S. B.; Dongare, M. K.; Biradar, A. V.; Kulal, A. Kotbagi, T. V.; Bhosale, A.R.; Chandgude, M. G. “Sol-gel synthesized WO3/SiO2 catalysts for nitration of aromatics” US Patent 9,409,854 B2 Granted
- Biradar, A. V.; Umbarkar, S. B.; Chandra, P. Corrugated silica nanospheres for metal free epoxidation of olefins and process thereof” IN201301389-I1
- Asefa, T.; Biradar, A. V.; “Gold nanocatalysts and methods of use thereof” Patent publication US 2012/0289749 A1
- Asefa, T. Biradar, A. V.; Wang, Y.; “Efficent and recyclable heterogeneous nanocatalysts” US pat.no US9283545 B2 USA Granted
- Umbarkar, S. B.; Dongare, M. K.; Biradar, A. V.; Acham, V. R. “Process for preparation of organometallic molybdenum acetylidedioxo complex, (h5-C5H5)MoO2(-CºCPh) a catalysts for oxidation reactions using molybdenum oxide precursor. Publication no and date WO2012035555 (A1) 2012-03-22, IND patent no 293813 Granted
- Umbarkar, S. B.; Dongare, M. K.; Biradar, A. V. “An improved process for the preparation of high selective diphenyl oxalate. Pat. No 256642 Granted
Book Chapters:
1. Asefa, T.*; Biradar, A. V.; Das, S.; Sharma, K. K.; Silva, R. “Nanocatalysts for the Heck Coupling Reactions” Book Chapter in “Nanocatalysis: Synthesis and Applications” (V. Polshettiwar, T. Asefa, eds.), John Wiley & Sons, Inc., 2013, 11-50
2. Asefa, T.*; Biradar, A. V.; Das, S.; Sharma, K. K. “Nanostructured Catalysts for the Henry, Aldol, and Knoevenagel Reactions” Book Chapter in “Nanocatalysis: Synthesis and Applications” (V. Polshettiwar, T. Asefa, eds.), John Wiley & Sons, Inc., 2013, 221-250
- Homogeneous and heterogeneous catalysis, Synthesis and characterization of Nanomaterials: Nanoporous materials (e.g. MCM, SBA and Silica sphere), core-shell (silica, ceria and zirconia) shaped nanoparticles, (Nano Particles: Au, Pd, Co), organometallic complexes, supported heterogeneous catalysts, Techniques: Sol-gel, Co-precipitation, Post-grafting, Catalysis: Oxidation, Dehydrogenation, Hydrogenation, Carbonylation, Amination, Suzuki coupling, Nitro-aldol reactions, Biocatalysis etc., Gas phase, High pressure reactions.
- Heterogeneous Catalysis , Synthesis and characterization of Nano, Multifunctional Catalysts (Carbon, Silica, Ceria and Zirconia), Catalysis: Oxidation, Dehydrogenation, Hydrogenation, Carbonylation, Amination, Nitration, Nitro-aldol reactions etc. Gas phase and High Pressure reactions Bio-Materials synthesis
- Others
